ESPNU lists St. Louis vs. Temple men at that time slot for Saturday. As far as I know, the only video available will be the free Big East network online. You only need to register once and you can see whatever game they are featuring each week.
Not sure who the announcers will be, but at least you won't be watching a Pitt video feed with their announcers doing the call.
The six o'clock game time made this a trip worth staying home and watching on the computer, rather than driving in the dark and getting home well after mid-night after spending most of the afternoon driving out there. A 2 p.m. game and I would have done it.